Richard D. Adams, Joseph Kiprotich, Dmitry V. Peryshkov, Yuen Onn Wong, Opening of Carborane Cages by Metal Cluster Complexes: The Reaction of a Thiolate-Substituted Carborane with Triosmium Carbonyl Cluster Complexes, Inorganic Chemistry, 10.1021/acs.inorgchem.6b01403, 55, 16, (8207-8213), (2016). Fullerenes containing metal atoms and clus- ters can be … The term “metal atom cluster” was introduced in 1964 by F. A. Metal Atoms and Clusters in Fullerene Cages Donald S. Bethune, Costantino S. Yannoni, Mark Hoinkis, Mattanjah de Vrics, Jesse R. Salem, Mark S. Crowder x and Robert D. Johnson IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120-6099 "IBM Adstar, 5600 Cotfle Rd., San Jose, CA 95193 Received 20 September 1992 Abstract. Formation of Metal-Encapsulating Si Cage Clusters Hidefumi Hiura,1,* Takehide Miyazaki,2 and Toshihiko Kanayama3 1Joint Research Center for Atom Technology (JRCAT)-Angstrom Technology Partnership, Tsukuba 305-0046, Japan 2Electrotechnical Laboratory, 1-1-4 Umezono, Tsukuba 305-8568, Japan 3JRCAT-National Institute for Advanced Interdisciplinary Research, 1-1-4 Higashi, Tsukuba 305 … Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. Cotton to designate a finite group of metal atoms held together mainly, or at least to a significant extent, by metal-metal bonds. NON-METAL RINGS, CAGES AND CLUSTERS J. D. Woollins Department of Chemistry Imperial College of Science and Technology, South Kensington, London SW7 2AY John Wiley & Sons Chichester • New York • Brisbane • Toronto • Singapore . The reaction of … While hollow icosahedral cages in metal clusters have been found, they are rather unusual for Ag or Au clusters (vide infra). That was necessary in order to differentiate this emerging class of compounds from polynuclear complexes in which the metal centers are held together exclusively or mainly by bridging ligands. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. Opening of Carborane Cages by Metal Cluster Complexes: The Reaction of a Thiolate-Substituted Carborane with Triosmium Carbonyl Cluster Complexes. Adams RD(1), Kiprotich J(1), Peryshkov DV(1), Wong YO(1). Author information: (1)Department of Chemistry and Biochemistry, University of South Carolina , Columbia, South Carolina 29208, United States. Hence, these hollow coinage–metal (Ag and Au) icosahedral cages represent the first examples of its kind.

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